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Wastewater Treatment Plants (H₂S)

ISO 9223C4· HighC5· Very high

Why H₂S is so hard on copper

Hydrogen sulphide reacts with copper even at low concentrations, forming a black copper sulphide layer that does not protect the metal underneath. Copper tubes thin, return bends and brazed joints leak, and on copper-tube coils the fin collars lose contact.

Where H₂S is oxidised by bacteria on wet surfaces, sulphuric acid forms as well, which attacks aluminium fins and steel casings.

Plant areas are not equal

H₂S is released where sewage is agitated or sludge is stored and treated. Equipment next to inlet works, sludge thickening and dewatering, and odour-control units sees the highest levels. Office and control buildings are exposed through their outdoor-air intakes.

Illustrative image

ISO 9223 corrosivity category

Typical category for this environment: C4–C5.

  1. C1Very low
  2. C2Low
  3. C3Medium
  4. C4High
  5. C5Very high
  6. CXExtreme
ISO 9223 atmospheric corrosivity categories

Recommended protection by plant area

ConditionISO 9223Recommended systemNote
Inlet works, sludge handling, odour controlC5PG-C
Air-dry 2K
Highest H₂S levels; review coil material too.
Other outdoor units on siteC4PG-C
Air-dry 2K
H₂S drifts across the site with the wind.
Control rooms and offices (filtered air)C4PG-S1
Polysiloxane sol-gel
Outdoor air intakes carry H₂S indoors.
Site corrosivity estimator

Not sure which category your site falls into?

Enter distance from the sea, humidity and nearby industry to get an estimated ISO 9223 category.

Estimate your site
Are copper-fin coils better at wastewater plants?

No. Copper-fin coils remove the copper–aluminium couple but put more copper into an atmosphere that attacks copper. Coating is needed either way.

Does ISO 9223 cover H₂S?

Not directly. ISO 9223 is based on sulphur dioxide and chlorides. For electronics, ISA-71.04 classifies gaseous contaminants including H₂S; for coils, treat sites with noticeable H₂S as at least C5.

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